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UCL Discovery
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  • Pressure-driven fragmentation of multiphase clouds at high redshift

    The discovery of a hyper metal-poor star with total metallicity of ≤10−5 Z⊙ has motivated new investigations of how such objects can form from primordial gas polluted by a single supernova. In this paper, we present a shock-cloud model which simulates a supernova remnant interacting with a cloud in a metal-free environment at redshift z = 10. Pre-supernova conditions are considered, which include a multiphase neutral medium and H ii region. A small dense clump (n = 100 cm−3), located 40 pc fr...

    Development of clinically relevant testing methods for the fatigue performance for tibial trays.

    This thesis investigates whether the testing method proposed by the International Standards Organisation (ISO) for determining the fatigue performance of total knee tibial trays is clinically relevant, and if so what would be the appropriate load for testing. Fracture of tibial trays occurs for a number of reasons. These include poor design, insufficient support beneath the tray, inadequate manufacturing and material properties, malalignment, incomplete coverage of the tibial plateau, and ove...

    Class of antiretroviral drugs and the risk of myocardial infarction

    BACKGROUND:We have previously demonstrated an association between combination antiretroviral therapy and the risk of myocardial infarction. It is not clear whether this association differs according to the class of antiretroviral drugs. We conducted a study to investigate the association of cumulative exposure to protease inhibitors and nonnucleoside reverse-transcriptase inhibitors with the risk of myocardial infarction.METHODS:We analyzed data collected through February 2005 from our prospe...

    Part I: Synthesis of novel purely planar chiral ferrocenes for aysymetric synthesis: Part II: Synthesis of novel azaferrocenylboronic acids

    Part I : Synthesis of Novel Purely Planar Chiral Ferrocenes for Asymmetric Synthesis The first part of the thesis describes the design and synthesis of a series of 1,2-bidendate purely planar chiral ferrocenyl ligand (Ligand A, B, C). The planar chirality was established using Kagan’s Directed ortho Metallation (DoM) strategy. Introduction of the desired α–cyclopentadienyl moiety proved to be difficult using nucleophilic substitution. This was circumvented by utilising Stone’s fulvene form...
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