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Caltech Authors
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  • Band convergence in the non-cubic chalcopyrite compounds Cu_2MGeSe_4

    Inspired by recent theoretical predictions on band convergence in the tetragonal chalcopyrite compounds, we have explored the influence of the crystal structure on the transport and bandstructure of different quaternary chalcopyrites. In theory, a changing lattice parameter ratio of c/2a towards unity should lead to band convergence due to a more cubic and higher symmetry structure. In accordance with this prediction, the different solid solutions explored in this manuscript show a significan...

    The role of vibrational–rotational coupling in V–V and V–R,T energy transfer

    The effect of neglecting vibrational–rotational coupling in energy transfer calculations is studied for collisions of HF (v=1–7) with HF (v=0). An analog of a "classical path" method is considered in which rigid-rotor trajectories are used to determine a time-dependent forcing term on the vibrational motion of each molecule. The results are compared with our quasiclassical calculations in which no such approximation was used. At higher vibrational states the rigid-rotor forced-oscillator mode...

    Quantal Response Equilibrium

    A quantal response specifies choice probabilities that are smooth, increasing functions of expected payoffs. A quantal response equilibrium has the property that the choice distributions match the belief distributions used to calculate expected payoffs. This stochastic generalization of the Nash equilibrium provides strong empirical restrictions that are generally consistent with data from laboratory experiments with human subjects. We define the concept of regular quantal response equilibriu...

    Osmium isotopes in hydrothermal fluids from the Juan de Fuca Ridge

    We present Os data for axial high-temperature and off-axial low-temperature hydrothermal solutions from the Juan de Fuca Ridge. The high-temperature, H₂S-bearing axial fluids have unradiogenic Os isotopes pointing to a nearly complete domination of osmium isotopes from the basalts during hydrothermal circulation. The ridge axis fluids typically do not show large enrichment in osmium concentration over seawater although one high-temperature fluid has an Os concentration enhanced by a factor of...
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