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Caltech Authors
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  • Electrolytic decomposition and photodecomposition of compound semiconductors in contact with electrolytes

    Gerischer, Heinz (1978)
    Electrons and holes affect the bond strength of surface atoms. Therefore, in most systems their surface concentration controls the rate of electrolytic decomposition reactions. The thermodynamics of such reactions are characterized by their redox potentials which are equivalent to the Fermi energies of electrons or holes. It is shown that the energy positions of the redox Fermi levels for decomposition with respect to the position of the band edges and the Fermi levels of competing redox reac...

    The Habitable Exoplanet (HabEx) Imaging Mission: preliminary science drivers and technical requirements

    Mennesson, Bertrand; Mawet, Dimitri (2016)
    HabEx is one of four candidate flagship missions being studied in detail by NASA, to be submitted for consideration to the 2020 Decadal Survey in Astronomy and Astrophysics for possible launch in the 2030s. It will be optimized for direct imaging and spectroscopy of potentially habitable exoplanets, and will also enable a wide range of general astrophysics science. HabEx aims to fully characterize planetary systems around nearby solar-type stars for the first time, including rocky planets, po...

    Charge-localized p-phenylenedihydrazine radical cations: ESR and optical studies of intramolecular electron transfer rates

    Nelsen, Stephen F.; Ismagilov, Rustem F.; Powell, Douglas R. (1997)
    1,4-Bis(2-tert-butyl-2,3-diazabicyclo[2.2.2]oct-3-yl)benzene-1,4-diyl (2) its 2,5-dimethyl and 2,3,5,6-tetramethyl derivatives (3 and 4), their radical cations, and bis-radical dications are studied. Crystal structures including those of 2^+BPh_4^-, 3^(2+)(BPh_4^-)_2, 4^+BPh_4^-, and 4^(2+)(BPh_4^-)_2 establish that ring methylation causes more N-lone pair, aryl π twist without changing the NAr,NAr distance significantly and that both 2^+ and 4^+ have the charge localized in one hydrazine uni...

    The H1-compact global attractor for the solutions to the Navier-Stokes equations in two-dimensional unbounded domains

    Ju, Ning (2000)
    We extend previous results obtained by Rosa (1998 Nonlinear Anal. 32 71-85) on the existence of the global attractor for the two-dimensional Navier-Stokes equations on some unbounded domains. We show that if the forcing term is in the natural space H, then the global attractor is compact not only in the L2 norm but also in the H1 norm, and it attracts all bounded sets in H in the metric of V. The proof is based on the concept of asymptotic compactness and the use of the enstrophy equation. As...

    On distributed scheduling in wireless networks exploiting broadcast and network coding

    Cui, Tao; Chen, Lijun; Ho, Tracey (2010)
    In this paper, we consider cross-layer optimization in wireless networks with wireless broadcast advantage, focusing on the problem of distributed scheduling of broadcast links. The wireless broadcast advantage is most useful in multicast scenarios. As such, we include network coding in our design to exploit the throughput gain brought in by network coding for multicasting. We derive a subgradient algorithm for joint rate control, network coding and scheduling, which however requires centrali...
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