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Discovery Projects - Grant ID: DP130100483

Title
Discovery Projects - Grant ID: DP130100483
Funding
ARC | Discovery Projects
Contract (GA) number
DP130100483
Start Date
2013/01/01
End Date
2015/12/31
Open Access mandate
no
Organizations
-
More information
http://purl.org/au-research/grants/arc/DP130100483

 

  • Solvent promoted reversible cyclometalation in a tethered NHC iridium complex

    Reaction of [Ir(COD)(py–ItBu)]+ (py–ItBu = 3-tert-butyl-1-picolylimidazol-2-ylidene) with acetonitrile results in reversible intramolecular C–H bond activation of the NHC ligand and formation of [Ir(η2:η1-C8H13)(py–ItBu′)(NCMe)]+. Coordinated COD acts as an internal hydride acceptor and acetonitrile coordination offsets the otherwise unfavourable thermodynamics of the process.
  • No project research data found
  • Scientific Results

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    PUBLICATIONS BY ACCESS MODE

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    Publications in Repositories

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