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Publisher: Altai State University
Journal: Khimiia rastitel'nogo syr'ia (Chemistry of plant raw material)
Languages: Russian
Types: Article
Subjects: enzyme, horseradish peroxidase, guaiacol, oxidative coupling., фермент, пероксидаза хрена, гваякол, окислительное сочетание.
Методом газовой хроматомасс-спектрометрии установлен компонентный состав продуктов пероксидазного окисления гваякола в водных растворах и смесях воды с диметилсульфоксидом (ДМСО). В качестве начальных продуктов реакции окислительного сочетания гваякола идентифицированы пять димерных соединений. Дейтерирование продуктов реакции и анализ масс-спектров полученных производных позволили идентифицировать два компонента как простые эфиры и три соединения, принадлежащих к классу диметоксидифенилов. Для системы вода – ДМСО показано, что состав продуктов реакции сохраняется при переходе от водного к водно-органическому растворителю с содержанием органической фазы до 30%.
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

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