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Радбиль, Аркадий Беньюминович; Долинский, Тарас Иванович; Новоселов, Артем Сергеевич; Маврина, Екатерина Александровна; Шалашова, Александра Аркадьевна; Ильичев, Илья Сергеевич; Сулимов, Александр Владимирович; Смирнов, Василий Филиппович; Смирнова, Ольга Николаевна (2014)
Publisher: Altai State University
Journal: Khimiia rastitel'nogo syr'ia (Chemistry of plant raw material)
Languages: Russian
Types: Article
Subjects: скипидар; α-пинен; α-терпинеол; гидратация; катализ, turpentine, α-pinene, α-terpineol, hydration, catalysis
Physical and chemical regularities of synthesis of monoterpenic alcohols by turpentine hydration at a catalysis ortofosforny acid are studied. Influencing of concentration of the catalyst, the water module, temperature and hydration duration on structure and quantity of received products is reviewed. Conditions of obtaining monoterpene alcohols are recommended: the concentration of catalyst aqueous solution – 40%, the temperature – 65 °C, the duration of the synthesis – 4 hours, the water module – 1 : 1, the amount of emulsifier – 0,3% by volume phosphoric acid. Crystallization a-terpineol from reaction mixtures with a high content of terpene alcohols studied. Basic physical and chemical characteristics of the products obtained are identified and their fungicidal and bactericidal activity was studied.
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

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    • Received September 9, 2014 Revised October 9, 2014
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