Remember Me
Or use your Academic/Social account:


Or use your Academic/Social account:


You have just completed your registration at OpenAire.

Before you can login to the site, you will need to activate your account. An e-mail will be sent to you with the proper instructions.


Please note that this site is currently undergoing Beta testing.
Any new content you create is not guaranteed to be present to the final version of the site upon release.

Thank you for your patience,
OpenAire Dev Team.

Close This Message


Verify Password:
Verify E-mail:
*All Fields Are Required.
Please Verify You Are Human:
fbtwitterlinkedinvimeoflicker grey 14rssslideshare1
Yao, Zhixiao; Miras, Haralampos N.; Song, Yu-Fei (2016)
Publisher: R S C Publications
Languages: English
Types: Article
The increasingly stringent regulations in relation to the environmental impact of employed industrial processes make compulsory the development of alternative routes towards the reduction of sulfur and nitrogen contents in large scale chemical mixtures. Herein, we demonstrate for the first time the highly efficient application of polyoxometalate (POMs)/layered double hydroxide (LDHs) composites in deep desulfurization (1000 ppm) and denitrogenation (100 ppm) of a complex model oil system under mild conditions (65 °C), with a corresponding decrease of the content to less than 10 and 1 ppm, respectively. The high efficiency of the heterogeneous catalyst along with the high stability and easy recovery of the catalytic system renders them promising candidates for greener catalytic applications.
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

    • Acknowledgements 20 M. Huang, G. Chang, Y. Su, H. Xing, Z. Zhang, Y. Yang, Q. Ren, Z. Bao and B. Chen, Chem. Commun. 2015, 51, 12205-12207.
    • This work was supported by National Basic Research Program 21 L.-L. Xie, A. Favre-Réguillon, X.-X. Wang, X. Fu, S. Pellet(973 program, 2014CB932104), National Science Foundation of Rostaing, G. Toussaint, C. Geantet, M. Vrinat and M. Lemaire, China (21222104, U1407127), the Fundamental Research Green Chem. 2008, 10, 524-531. 22 L.-L. Xie, A. Favre-Réguillon, S. Pellet-Rostaing, X.-X. Wang, X.
    • Funds for the Central Universities (RC1302, YS1406) and Fu, J. Estager, M. Vrinat and M. Lemaire, Ind. Eng. Chem. Res.
    • Beijing Engineering Centre for Hierarchical Catalysts. H.N.M 2008, 47, 8801-8807.
    • acknowledges the financial support from University of 23 H. Wang, C. Xie, S. Yu and F. Liu, Chem. Eng. J. 2014, 237, Glasgow. 286-290. 24 H. Gao, C. Guo, J. Xing, J. Zhao and H. Liu, Green Chem. 2010, 12, 1220-1224.
    • Notes and references 25 YC.hiNniae.,CXh.eGmo.,n2g0,1H4., S5.7G,1a7o6,6X-.1P7.73Z.hang and S. J. Zhang. Sci. 26 L. Kong, G. Li and X. Wang, Catal. Today 2004, 93-95, 341-
    • 1 P. Wiwel, K. Knudsen, P. Zeuthen and D. Whitehurst, Ind. 345. Eng. Chem. Res. 2000, 39, 533-540. 27 C. Komintarachat and W. Trakarnpruk, Ind. Eng. Chem. Res.
    • 2 X. Ma, S. Velu, J. H. Kim and C. Song, Appl. Catal. B: Environ. 2006, 45, 1853-1856. 2005, 56, 137-147. 28 A. M. Khenkin and R. Neumann, ChemSusChem 2011, 4, 346-
    • 3 K. A. Cychosz, A. G. Wong-Foy and A. J. Matzger, J. Am. 348. Chem. Soc. 2008, 130, 6938-6939. 29 Y. Shiraishi, K. Tachibana, T. Hirai and I. Komasawa, Ind. Eng.
    • 4 X. Xu, J. A. Moulijn, E. Ito, R. Wagemans and M. Makkee, Chem. Res. 2002, 41, 4362-4375. ChemSusChem. 2008, 1, 817-819. 30 W.-H. Lo, H.-Y. Yang and G.-T. Wei, Green Chem. 2003, 5,
    • 5 M. S. Shannon, A. C. Irvin, H. Liu, J.D. Moon, M. S. Hindman, 639-642. C. H. Turner and J. E. Bara, Ind. Eng. Chem. Res. 2015, 54, 31 W. Zhu, H. Li, X. Jiang, Y. Yan, J. Lu, L. He and J. Xia, Green 462-471. Chem. 2008, 10, 641-646.
    • 6 X. Liu, X. Li and Z. Yan, Appl. Catal. B: Environ. 2012, 121-122, 32 W. Huang, W. Zhu, H. Li, H. Shi, G. Zhu, H. Liu and G. Chen, 50-56. Ind. Eng. Chem. Res. 2010, 49, 8998-9003.
    • 7 R. T. Yang, A. J. Hernandez-Maldonado and F. H. Yang, 33 J. Xu, S. Zhao, W. Chen, M. Wang and Y.-F. Song, Chem. Eur. Science 2003, 301, 79-81. J. 2012, 18, 4775-4781.
    • 8 T. A. Zepeda, B. Pawelec, R. Obeso-Estrella, J. N. Díaz de 34 J. Xu, S. Zhao, Y. Ji and Y.-F. Song, Chem. Eur. J. 2013, 19, 709- León, S. Fuentes, G. Alonso-Núnez and J. L. G. Fierro, Appl. 715. Catal. B: Environ. 2016, 180, 569-579. 35 Y. Chen, S. Zhao and Y.-F. Song, Appl. Catal. A-Gen. 2013,
    • 9 N.-Q. Bui, C. Geantet and G. Berhault, J. Catal. 2015, 330, 466, 307-314. 374-386. 36 H. N. Miras, L. Vila-Nadal and L. Cronin, Chem. Soc. Rev.
    • 10 A. Rothlisberger and R. Prins, J. Catal. 2005, 235, 229-240. 2014, 43, 5679-5699.
    • 11 D. Liu, J. Gui and Z. Sun, J. Mol. Catal. A-Chem. 2008, 291, 17- 37 S. S. Wang and G. Y. Yang, Chem. Rev. 2015, 115, 4893-4962. 21. 38 S. Herrmann, M. Kostrzewa, A. Wierschem and C. Streb,
    • 12 R. G. Pearson, J. Am. Chem. Soc. 1963, 85, 3533-3539. Angew. Chem. Int. Ed. 2014, 53, 13596-13599.
    • 13 W. Kaernbach, W. Kisielow, L. Warzecha, K. Miga, R. Klecan, 39 H. N. Miras, J. Yan, D. L. Long and L. Cronin, Chem. Soc. Rev. Fuel 1990, 69, 221-224. 2012, 41, 7403-7430.
    • 14 M. Macaud, M. Sévignon, A. Favre-Réguillon, M. Lemaire, E. 40 J. Han, Y. Dou, M. Wei, D. G. Evans and X. Duan, Angew. Schulz and M. Vrinat, Ind. Eng. Chem. Res. 2004, 43, 7843- Chem. Int. Ed. 2010, 49, 2171-2174. 7849. 41 P. Liu, H. Wang, Z. Feng, P. Ying and C. Li, J. Catal. 2008, 256,
    • 15 A. J. Hernandez-Maldonado and R. T. Yang, Angew. Chem. 345-348. Int. Ed. 2004, 43, 1004-1006. 42 P. Liu, C. Wang and C. Li, J. Catal. 2009, 262, 159-168.
    • 16 A. J. Hernández-Maldonado and R. T. Yang, Ind. Eng. Chem. 43 S. Zhao, J. Xu, M. Wei and Y.-F. Song, Green Chem. 2011, 13, Res. 2003, 42, 3103-3110. 384-389.
    • 17 J. A. Arcibar-Orozco and J. R. Rangel-Mendez, Chem. Eng. J. 44 Y. Chen, Z. Yao, H. N. Miras and Y.-F. Song, Chem. Eur. J. 2013, 230, 439-446. 2015, 21, 10812-10820.
    • 18 X. Han, H. Lin and Y. Zheng, Chem. Eng. J. 2014, 243, 315- 45 M. Li, M. Zhang, A. Wei, W. Zhu, S. Xun, Y. Li, H. Li and H. Li, 325. 46 X. Zhang, Y. Shi and G. Liu, Catal. Sci. Technol. 2016, 6, 1016- 19 M. Maes, M. Trekels, M. Boulhout, S. Schouteden, F. 1024. Vermoortele, L. Alaerts, D. Heurtaux, Y. K. Seo, Y. K. Hwang, J. S. Chang, I. Beurroies, R. Denoyel, K. Temst, A. Vantomme, P. Horcajada, C. Serre and D. E. De Vos, Angew. Chem. Int. Ed. 2011, 50, 4210-4214.
  • No related research data.
  • No similar publications.

Share - Bookmark

Cite this article