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Syme, Christopher D.; Mosses, Joanna; Gonz?lez-Jim?nez, Mario; Shebanova, Olga; Walton, Finlay; Wynne, Klaas (2017)
Publisher: Nature Publishing Group
Journal: Scientific Reports
Languages: English
Types: Article
Subjects: Article

Classified by OpenAIRE into

arxiv: Physics::Fluid Dynamics, Condensed Matter::Soft Condensed Matter, Condensed Matter::Disordered Systems and Neural Networks, Physics::Chemical Physics
Frustration of crystallisation by locally favoured structures is critically important in linking the phenomena of supercooling, glass formation, and liquid-liquid transitions. Here we show that the putative liquid-liquid transition in n-butanol is in fact caused by geometric frustration associated with an isotropic to rippled lamellar liquid-crystal transition. Liquid-crystal phases are generally regarded as being “in between” the liquid and the crystalline state. In contrast, the liquid-crystal phase in supercooled n-butanol is found to inhibit transformation to the crystal. The observed frustrated phase is a template for similar ordering in other liquids and likely to play an important role in supercooling and liquid-liquid transitions in many other molecular liquids.
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