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Carbone, Giorgio; Burnley, James; Moses, John E. (2013)
Publisher: Thieme Chemistry
Languages: English
Types: Article
Subjects:
The reduction of a range of substituted azidonitrobenzene derivatives to the corresponding aniline is described. The chemoselective reaction proceeds cleanly and in good yield, generating minimal waste products. The process involves a thiazolium salt derived species which is proposed as a radical anion relay, with tert-butoxide as the stoichiometric reductant.

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