Remember Me
Or use your Academic/Social account:


Or use your Academic/Social account:


You have just completed your registration at OpenAire.

Before you can login to the site, you will need to activate your account. An e-mail will be sent to you with the proper instructions.


Please note that this site is currently undergoing Beta testing.
Any new content you create is not guaranteed to be present to the final version of the site upon release.

Thank you for your patience,
OpenAire Dev Team.

Close This Message


Verify Password:
Verify E-mail:
*All Fields Are Required.
Please Verify You Are Human:
fbtwitterlinkedinvimeoflicker grey 14rssslideshare1
Publisher: Royal Society of Chemistry
Languages: English
Types: Article
Subjects: QD
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

    • should favour more tailored approaches to not only optimise 20 A. G. M. Barrett, M. R. Crimmin, M. S. Hill, P. B. Hitchcock and catalyst activity but also control the outcome of such dehydro- P. A. Procopiou, Organometallics, 2007, 26, 4076-4079.
    • coupling reactions. 21 J. Spielmann and S. Harder, J. Am. Chem. Soc., 2009, 131, Future work in the area of main group catalysis should focus on 5064-5065.
    • the development of new types of E-E0 bond-forming reactions and 22 P. Bellham, M. S. Hill, G. Kociok-Ko¨hn and D. J. Liptrot, the optimisation of catalyst activity. With regard to the latter, unlike Chem. Commun., 2013, 49, 1960-1962.
    • transition metal chemistry, it should be noted that there have been 23 P. C. Keller, Inorg. Synth., 1977, 17, 30.
    • no previous systematic attempts to vary the ligand set in order to 24 H. J. Cowley, M. S. Holt, R. L. Melen, J. M. Rawson and optimise activity of main group metal catalysts. As is already apparent D. S. Wright, Chem. Commun., 2011, 47, 2682-2684.
    • from studies so far, changing the steric demands of the ligands in 25 M. M. Hansmann, R. L. Melen and D. S. Wright, Chem. Sci., the pre-catalysts is one obvious way of modifying both the kinetics 2011, 2, 1554-1559.
    • and selectivity. However, a further way of enhancing activity in the 26 R. J. Less, H. R. Simmonds and D. S. Wright, Dalton Trans., future is to control the Lewis acidity of the metal centres, and 2014, 43, 5785-5792.
    • increase redox stability. This would lead to greater polarisation of 27 C. A. Jaska, K. Temple, A. J. Lough and I. Manners, J. Am.
    • metal-bonded intermediates and potentially longer catalyst life-times. Chem. Soc., 2003, 125, 9424-9434. 28 R. L. Melen, Dalton Trans., 2014, 42, 16449-16465.
    • 29 K. A. Erickson, D. S. Wright and R. Waterman, J. Organomet.
    • References Chem., 2014, 751, 541-545. 30 D. W. Stephan and G. Erker, Angew. Chem., Int. Ed., 2015, 54,
    • 1 E. M. Leitao, T. Jurca and I. Manners, Nat. Chem., 2013, 5, 6400-6441, and references therein. 817-829, and references therein. 31 C. Appelt, J. C. Slootweg, K. Lammertsma and W. Uhl, 2 T. R. Hogness, T. L. Wilson and W. C. Johnson, J. Am. Chem. Angew. Chem., Int. Ed., 2013, 52, 4256-4259. Soc., 1936, 58, 108-112. 32 A. J. M. Miller and J. E. Bercaw, Chem. Commun., 2010, 46, 3 C. H. Lewis, H. C. Kelly, M. B. Giusto and S. Johnson, 1709-1711. J. Electrochem. Soc., 1961, 108, 1114-1118. 33 J.-M. Denis, H. Forintos, H. Szelke, L. Toupet, T.-N. Pham, P.-J.
    • 4 N. N. Greenwood and R. Greatrex, Pure Appl. Chem., 1987, Madec and A.-C. Gaumont, Chem. Commun., 2003, 54-55. 59, 857-868. 34 H. Dorn, R. A. Singh, J. A. Massey, J. M. Nelson, C. A. Jaska, A. J.
    • 5 Chemistry of the elements, ed. N. N. Greenwood and Lough and I. Manners, J. Am. Chem. Soc., 2000, 122, 6669-6678. A. Earnshaw, Butterworth-Heinemann, Oxford, 2nd edn, 1997. 35 S. C. Shit and P. Shah, Natl. Acad. Sci. Lett., 2013, 36, 355-365.
    • 6 Compiled E-H bond enthalpies drawn from multiple sources. 36 J. M. Blackwell, K. L. Foster, V. H. Beck and W. E. Piers, 7 L. S. Kassel, J. Am. Chem. Soc., 1932, 54, 3949-3961. J. Org. Chem., 1999, 64, 4887-4892.
    • 8 K. Tamaru, M. Boudart and H. Talor, J. Phys. Chem., 1955, 37 For example see: D. J. Parks, J. M. Blackwell and W. E. Piers, 59, 801-805. J. Org. Chem., 2000, 65, 3090-3098.
    • 9 C. W. Hamilton, R. T. Baker, A. Staubitz and I. Manners, 38 X. Luo and R. H. Crabtree, J. Am. Chem. Soc., 1989, 111, Chem. Soc. Rev., 2009, 38, 279-293, and references therein. 2527-2535.
    • 10 T. J. Clark, K. Lee and I. Manners, Chem. - Eur. J., 2006, 12, 39 For example see: T. B. Gregg and A. R. Cutler, Organometallics, 8634-8648, and references therein. 1994, 13, 1039-1043.
    • 11 R. Waterman, Chem. Soc. Rev., 2013, 42, 5629-5641. 40 R. H. Crabtree, Angew. Chem., Int. Ed., 1993, 32, 789-805.
    • 12 G. Wolf, J. Baumann, F. Baitalow and F. P Hoffmann, 41 J. Cella and S. Rubinsztajn, Macromolecules, 2008, 41, 6965-6971. Thermochim. Acta, 2000, 343, 19-25. 42 M. P´erez, C. B. Caputo, R. Dobrovetsky and D. W. Stephan, 13 R. J. Less, R. L. Melen and D. S. Wright, RSC Adv., 2012, 2, Proc. Natl. Acad. Sci. U. S. A., 2014, 111, 10917-10921. 2191-2199, and references therein. 43 D. J. Harrison, D. R. Edwards, R. McDonald and L. Rosenberg, 14 D. J. Liptrot, M. S. Hill, M. F. Mahon and D. J. MacDougall, Dalton Trans., 2008, 3401-3411. Chem. - Eur. J., 2010, 16, 8508-8515. 44 P. T. K. Lee, M. K. Skjel and L. Rosenberg, Organometallics, 15 P. Bellham, M. S. Hill, D. J. Liptrot, D. J. MacDougall and 2013, 32, 1575-1578. M. F. Mahon, Chem. Commun., 2011, 47, 9060-9062. 45 R. Fessenden and J. S. Fessenden, Chem. Rev., 1961, 61, 16 M. S. Hill, M. Hodgson, D. J. Liptrot and M. F. Mahon, 361-388, and references therein. Dalton Trans., 2011, 40, 7783-7790. 46 L. Greb, S. Tamke and J. Paradies, Chem. Commun., 2014, 50, 17 H. Wadepohl, U. Kohl, M. Bittner and H. Koeppel, Organo- 2318-2320. metallics, 2005, 24, 2097-2105. 47 F. Buch and S. Harder, Organometallics, 2007, 26, 5132-5135.
    • 18 J. Spielmann, G. Jansen, H. Bandmann and S. Harder, 48 J. F. Dunne, S. R. Neal, J. Engelkemier, A. Ellern and Angew. Chem., Int. Ed., 2008, 47, 6290-6295. A. D. Sadow, J. Am. Chem. Soc., 2011, 133, 16782-16785.
    • 19 J. Spielmann, M. Bolteb and S. Harder, Chem. Commun., 49 M. S. Hill, D. J. Liptrot, D. J. MacDougall, M. F. Mahon and 2009, 6934-6936. T. P. Robinson, Chem. Sci., 2013, 4, 4212-4222.
  • No related research data.
  • Discovered through pilot similarity algorithms. Send us your feedback.

  • BioEntity Site Name
    2bh2Protein Data Bank

Share - Bookmark

Cite this article