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Sweetman, Adam; Stirling, Julian; Jarvis, Samuel Paul; Rahe, Philipp; Moriarty, Philip (2016)
Publisher: American Physical Society
Languages: English
Types: Article

Classified by OpenAIRE into

mesheuropmc: technology, industry, and agriculture, stomatognathic diseases, inorganic chemicals, equipment and supplies, complex mixtures
arxiv: Physics::Atomic and Molecular Clusters, Physics::Instrumentation and Detectors
It is generally accepted that the exposed surfaces of silicon crystals are highly reactive due to the dangling bonds which protrude into the vacuum. However, surface reconstruction can not only modify the reactivity of bulk silicon crystals, but plays a key role in determining the properties of silicon nanocrystals. In this study we probe the reactivity of silicon clusters at the end of a scanning probe tip by examining their interaction with closed shell fullerene molecules. Counter to intuitive expectations, many silicon clusters do not react strongly with the fullerene cage, and we find that only specific highly oriented clusters have sufficient reactivity to break open the existing carbon-carbon bonds.
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

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