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Delforge, Arnaud; Georgiou, Irene; Kremer, Adrian; Wouters, Johan; Bonifazi, Davide (2016)
Publisher: American Chemical Society
Languages: English
Types: Article
Subjects:
A Pd-catalyzed methodology for the preparation of tertiary enamides from acyclic secondary amides and bromo acrylates under mild reaction conditions has been developed using [Pd2(dba)3], XantPhos, and Ag2CO3 as a base. The reaction occurs through a stereospecific metal-mediated oxidative-insertion mechanism.
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