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fbtwitterlinkedinvimeoflicker grey 14rssslideshare1
Publisher: Elsevier
Journal: Science of The Total Environment
Languages: English
Types: Article
Subjects: Waste Management and Disposal, Environmental Engineering, Pollution, Environmental Chemistry
This study investigated the simultaneous removal of Sr2+ and 14CO32- from an alkaline (pH >12) Ca(OH)2 solution by the precipitation of calcium carbonate. Initial Ca2+:CO32- ratios ranged from 10:1 to 10:100 (mM: mM). Maximum removal of 14C and Sr2+ both occurred in the system containing 10 mM Ca2+ and 1 mM CO32- (99.7% and 98.6% removal, respectively). A kinetic model is provided that describes 14C and Sr removal in terms of mineral dissolution & precipitation reactions. The removal of 14C was achieved during the depletion of the initial TIC in solution, and was subsequently significantly affected by recrystallization of a calcite precipitate from an elongate to isotropic morphology. This liberated >46% of the 14C back to solution. Sr2+ removal occurred as Ca2+ became depleted in solution and was not significantly affected by the recrystallization process. This reaction could form the basis for low cost remediation scheme for 90Sr and 14C in radioactively contaminated waters (<$0.25 reagent cost per m3 treated).
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

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