Remember Me
Or use your Academic/Social account:


Or use your Academic/Social account:


You have just completed your registration at OpenAire.

Before you can login to the site, you will need to activate your account. An e-mail will be sent to you with the proper instructions.


Please note that this site is currently undergoing Beta testing.
Any new content you create is not guaranteed to be present to the final version of the site upon release.

Thank you for your patience,
OpenAire Dev Team.

Close This Message


Verify Password:
Verify E-mail:
*All Fields Are Required.
Please Verify You Are Human:
fbtwitterlinkedinvimeoflicker grey 14rssslideshare1
Wang, Yafei; Cabry, Christopher P.; Xiao, ManJun; Male, Louise; Cowling, Stephen J.; Bruce, Duncan W.; Shi, Junwei; Zhu, Weiguo; Baranoff, Etienne (2016)
Languages: English
Types: Article
Subjects: 1600
Blue- and green-emitting cyclometalated liquid-crystalline iridium complexes are realized by using a modular strategy based on strongly mesogenic groups attached to an acetylacetonate ancillary ligand. The cyclometalated ligand dictates the photophysical properties of the materials, which are identical to those of the parent complexes. High hole mobilities, up to 0.004 cm2 V-1 s-1, were achieved after thermal annealing, while amorphous materials show hole mobilities of only approximately 10-7-10-6 cm2 V-1 s-1, similar to simple iridium complexes. The design strategy allows the facile preparation of phosphorescent liquid-crystalline complexes with fine-tuned photophysical properties.
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

    • [1] C. Ulbricht, B. Beyer, C. Friebe, A. Winter, U. S. Schubert, Adv. Mater. 2009, 21, 4418-4441.
    • [2] H. Xu, R. Chen, Q. Sun, W. Lai, Q. Su, W. Huang, X. Liu, Chem. Soc. Rev. 2014, 43, 3259-3302.
    • [3] M. A. Baldo, D. F. OÕBrien, A. Shoustikov, S. Sibley, M. E. Thompson, R. S. Forrest, Nature 1998, 395, 151-154.
    • [4] D. Yokoyama, J. Mater. Chem. 2011, 21, 19187-19202.
    • [5] F. Steiner, S. Bange, J. Vogelsang, J. M. Lupton, J. Phys. Chem. Lett. 2015, 6, 999-1004.
    • [6] D. Yokoyama, H. Sasabe, Y. Furukawa, C. Adachi, J. Kido, Adv. Funct. Mater. 2011, 21, 1375-1382.
    • [7] C. Moon, K. Kim, J. W. Lee, J. Kim, J. Chem. Mater. 2015, 27, 2767- 2769.
    • [8] D. Yokoyama, Y. Setoguchi, A. Sakaguchi, M. Suzuki, C. Adachi, Adv. Funct. Mater. 2010, 20, 386-391.
    • [9] M. OÕNeil, S. M. Kelly, Adv. Mater. 2003, 15, 1135-1146.
    • [10] Y. Wang, J. Shi, J. Chen, W. Zhu, E. Baranoff, J. Mater. Chem. C 2015, 3, 7993-8005.
    • [11] S. Chen, H. Yuan, H. Zhuo, S. Chen, H. Yang, Z. Ge, J. Liu, J. Mate. Chem. C 2014, 2, 4203-4212.
    • [12] R. Bolleddu, M. Rabibrata, B. Dipankar, Soft Matter 2015, 11, 139-146.
    • [13] A. D’ez, S. J. Cowling, D. W. Bruce, Chem. Commun. 2012, 48, 10298- 10300.
    • [14] C. Damm, G. Israel, T. Heqmann, C. Tschierske, J. Mater. Chem. 2006, 16, 1808-1816.
    • [15] M. Krikorian, S. Liu, T. M. Swager, J. Am. Chem. Soc. 2014, 136, 2952.
    • [16] A. Santoro, A. C. Whitwood, J. A. G. Williams, V. Kozhevnikov, D. W. Bruce, Chem. Mater. 2009, 21, 3871-3882.
    • [17] V. Kozhevnikov, B. Donnio, D. W. Bruce, Angew. Chem. Int. Ed. 2008, 47, 6286-6289.
    • [18] E. I. Szerb, A. M. Talarico, I. Aiello, A. Crispini, N. Godbert, D. Pucci, T. Pugliese, M. Ghedini, Eur. J. Inorg. Chem. 2010, 21, 3270-3277.
    • [19] A. Santoro, A. Prokhorov, V. N. Kozhevnikov, A. C. Whitwood, B. Donnio, J. A. G. Williams, D. W. Bruce, J. Am. Chem. Soc. 2011, 133, 5248-5251.
    • [20] A. M. Prokhorov, A. Santoro, J. A. G. Williams, D. W. Bruce, Angew. Chem. Int. Ed. 2012, 51, 95-98.
    • [21] E. Baranoff, J. Voignier, T. Yasuda, V. Heitz, J. Sauvage, T. Kato, Angew. Chem. Int. Ed. 2007, 46, 4680-4683.
    • [22] M. Yoshio, Y. Shoji, Y. Tochigi, Y. Nishikawa, T. Kato, J. Am. Chem. Soc. 2009, 131, 6763-6767.
    • [23] Y. Molard, F. Dorson, V. C”rcu, T. Roisnel, F. Artzner, S. Cordier, Angew. Chem. Int. Ed. 2010, 49, 3351-3355.
    • [24] S. Campidelli, M. SŽverac, D. Scanu, R. Deschenaux, E. V‡squez, D. Milic, M. Prato, M. Carano, M. Marcaccio, F. Paolucci, G. M. Aminur Rahman, D. M. Guldi, J. Mater. Chem. 2008, 18, 1504-1509.
    • [25] E. Terazzi, C. Bourgogne, R. Welter, J.-L. Gallani, D. Guillon, G. Rogez, B. Donnio, Angew. Chem. Int. Ed., 2008, 47, 490-495.
    • [26] E. Baranoff, B. F. E. Curchod, J. Frey, R. Scopelliti, F. Kessler, I. Tavernelli, U. Rothlisberger, M. GrŠtzel, M. K. Nazeeruddin, Inorg. Chem. 2012, 51, 215-224.
    • [27] T. Tsuzuki, S. Tokito, Adv. Mater. 2007, 19, 276-280.
    • [28] E. Beltr‡n, M. Garzoni, B. Fering‡n, A. Vancheri, J. Barber‡, J. L. Serrano, G. M. Pavan, R. GimŽnez, T. Sierra, Chem. Commun. 2015, 51, 1811-1814.
    • [29] Y. Wang, J. Shi, J. Chen, W. Zhu, E. Baranoff, J. Mater. Chem. C 2015, 3, 7993-8005.
    • [30] W. Lee, T. Kwon, J. Kwon, J. Kim, C. Lee, J. Hong, New J. Chem. 2011, 35, 2557-2563.
    • [31] H. Zhen, Q. Hou, K. Li, Z. Ma, S. Fabiano, F. Gao, F. Zhang, J. Mater. Chem. A 2014, 2, 12390-12396.
    • [32] N. Wang, J. Yu, Y. Zheng, Z. Guan, Y. Jiang, J. Phys. Chem. C 2012, 116, 5887-5891.
    • [33] T. B. Fleetham, Z. Wang, J. Li, Inorg. Chem. 2013, 52, 7338-7343.
  • No related research data.
  • No similar publications.

Share - Bookmark

Cite this article