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Publisher: American Physics Society
Languages: English
Types: Article
Subjects:

Classified by OpenAIRE into

arxiv: Condensed Matter::Soft Condensed Matter, Physics::Fluid Dynamics
By perturbing about a general monodisperse system, we provide a complete description of two-phase equilibria in any system which is slightly polydisperse in some property (e.g., particle size, charge, etc.). We derive a universal law of fractionation which is corroborated by comprehensive experiments on a model colloid-polymer mixture. We furthermore predict that phase separation is an effective method of reducing polydispersity only for systems with a skewed distribution of the polydisperse property.
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