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Jana, A.; Pope, S.J.A.; Ward, M.D. (2017)
Publisher: Elsevier
Languages: English
Types: Article
Subjects:
A series of d/f dinuclear complexes Ir•Ln [where Ln = Eu(III), Gd(III), Yb(III) and Nd(III)] are reported. The core structure consists of a rigid skeleton containing two different types of receptor site in a single molecular motif designed to combine a transition metal ion [Ir(III)] and a lanthanide ion [Ln(III)] in different binding sites at either end of fully conjugated bridge to facilitate d→f energy-transfer following photoexcitation of the Ir(III)-based antenna unit. Steady state and time-resolved photophysical experiments on these compounds revealed that the energy-transfer is feasible only in case of Ir•Yb and Ir•Nd systems, affording sensitized emission from the Yb(III) or Nd(III) centres. Such EnT is not possible in the Ir•Eu dyad as the excited state energy of the Ir(III) unit is insufficient to sensitise the excited state of the Eu(III) centre.
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    • [1] [2] [3] (a) H. M. Kim, C. Jung, B. R. Kim, S.-Y. Jung, J. H. Hong, Y.-G. Ko, K. J. Lee, B.
    • R. Cho, Angew. Chem. Int. Ed. 46 (2007) 3460 3463; (b) H. M. Kim, M. J. An, J. H. Hong, B. H. Jeong, O. Kwon, J.-Y. Hyon, S.-C.
    • Hong, K. J. Lee, B. R. Cho, Angew. Chem. Int. Ed. 47 (2008) 2231 2234; (c) M. K. Kim, C. S. Lim, J. T. Hong, J. H. Han, H.-Y. Jang, H. M. Kim, B. R. Cho, Angew. Chem. Int. Ed. 49 (2010) 364 367; (d) H. J. Kim, J. H. Han, M. K. Kim, C. S. Lim, H. M. Kim, B. R. Cho, Angew.
    • Chem. Int. Ed. 49 (2010) 6786 6789; (e) G. Masanta, C. S. Lim, H. J. Kim, J. H. Han, H. M. Kim, B. R. Cho, J. Am.
    • Chem. Soc. 133 (2011) 5698 5700; (f) C. S. Lim, G. Masanta, H. J. Kim, J. H. Han, H. M. Kim, B. R. Cho, J. Am.
    • Chem. Soc. 133 (2011) 11132 11135; (g) H. J. Park, C. S. Lim, E. S. Kim, J. H. Han, T. H. Lee, H. J. Chun, B. R. Cho, Angew. Chem. Int. Ed. 51 (2012) 2673 2676; (h) S. K. Bae, C. H. Heo, D. J. Choi, D. Sen, E.-H. Joe, B. R. Cho, H. M. Kim, J.
    • Lippard, K. Okamoto, Proc. Natl. Acad. Sci. USA 111 (2014) 6786 6791; (j) L. Kong, Y.-P. Tian, Q.-Y. Chen, Q. Zhang, H. Wang, D.-Q. Tan, Z.-M. Xue, J.- Y. Wu, H.-P. Zhou, J.-X. Yang, J. Mater. Chem. C 3 (2015) 570 581.
    • (a) G. Zhou, D. Wang, X. Wang, X. Xu, Z. Shao, M. Jiang, Opt. Commun. 202 (2002) 221 225; (b) Q.-D. Chen, H.-H. Fang, B. Xu, J. Yang, H. Xia, F.-P. Chen, W.-J. Tian, H.-B.
    • Sun, Appl. Phys. Lett. 94 (2009) 201113-1 201113-3; (c) Y. Wang, T. Liu, L. Bu, J. Li, C. Yang, X. Li, Y. Tao, W. Yang, J. Phys. Chem.
    • C 116 (2012) 15576 15583.
    • Chem. Soc. 130 (2008) 2178 2179; (b) P. Verwilst, S. V. Eliseeva, L. Vander Elst, C. Burtea, S. Laurent, S. Petoud, R.
    • N. Muller, T. N. Parac-Vogt, W. M. De Borggraeve, Inorg. Chem. 51 (2012) 6405 6411; [4] [5] (c) M. Tropiano, C. J. Record, E. Morris, H. S. Rai, C. Allain, S. Faulkner, Organometallics 31 (2012) 5673 5676; (d) J. Luo, W.-S. Li, P. Xu, L.-Y. Zhang, Z.-N. Chen, Inorg. Chem. 51 (2012) 9508 9516; (e) X. Zhang, X. Jing, T. Liu, G. Han, H. Li, C. Duan, Inorg. Chem. 51 (2012) 2325 2331; (f) G. J. Stasiuk, F. Minuzzi, M. Sae-Heng, C. Rivas, H.-S. Juretschke, L. Piemonti, P. R. Allegrini, D. Laurent, A. R. Duckworth, A. Beeby, G. A. Rutter, N. J. Long, Chem. Eur. J. 21 (2015) 5023 5033; (g) A. Jana, E. Baggaley, A. Amoroso and M. D. Ward, Chem. Commun. 51 (2015) 8833 8836; (h) A. Jana, B. J. Crowston, J. Shewring, L. K. McKenzie, H. E. Bryant, S. W.
    • Botchway, A. J. Amoroso, E. Baggaley and M. D. Ward, Inorg. Chem. 55 (2016) 5623 5633.
    • (j) J. Luo, L.-F. Chen, P. Hu, Z.-N. Chen, Inorg. Chem. 53 (2014) 4184 4191; (a) J.-C. G. Bünzli, Chem. Rev. 110 (2010) 2729 2755; (b) E. J. New, D. Parker, D. G. Smith and J. W. Walton, Curr. Opin. Chem. Biol. 14 (2010) 238 246; (c) Q. Zhao, C. Huang and F. Li, Chem. Soc. Rev. 40 (2011) 2508 2524; (d) E. Baggaley, J. A. Weinstein and J. A. G. Williams, Coord. Chem. Rev. 256 (2012) 1762 1785; (e) M. P. Coogan and V. Fernández-Moreira, Chem. Commun. 50 (2014) 384 399.
    • A. Weinstein and J. A. G. Williams, Proc. Natl. Acad. Sci. USA 105 (2008) 16071 16076; (b) V. Fernández-Moreira, M. L. Ortego, C. F. Williams, M. P. Coogan, M. D.
    • Villacampa and M. C. Gimeno, Organometallics, 31 (2012) 5950 5957; (c) G. Li, Y. Chen, J. Wu, L. Ji and H. Chao, Chem. Commun. 49 (2013) 2040 2042; (d) S. J. Butler, L. Lamarque, R. Pal and D. Parker, Chem. Sci. 5 (2014) 1750 1756; [7] [8] [9] [10] [11] (e) E. Baggaley, M. R. Gill, N. H. Green, D. Turton, I. V. Sazanovich, S. W.
    • Chem., Int. Ed. 53 (2014) 3367 3371.
    • G. Williams and J. A. Weinstein, Chem. Sci. 5 (2014) 879 886; (b) E. Baggaley, M. R. Gill, N. H. Green, D. Turton, I. V. Sazanovich, S. W.
    • Chem. 53 (2014) 3367 3371.
    • Chem., Int. Ed. 44 (2005) 1806 1810; (b) E. Baggaley, D.-K. Cao, D. Sykes, S. W. Botchway, J. A. Weinstein and M. D.
    • Ward, Chem. Eur. J. 20 (2014) 8898 8903.
    • (a) M. D. Ward, Coord. Chem. Rev. 251 (2007) 1663 1677; (b) S. Faulkner, L. S. Natrajan, W. S. Perry, D. Sykes, Dalton Trans. 2009, 3890 3899; (c) M. D. Ward, Coord. Chem. Rev. 254 (2010) 2634 2642; (d) F.-F. Chen, Z.-Q. Chen, Z.-Q. Bian, C.-H. Huang, Coord. Chem. Rev. 254 (2010) 991 1010; (e) L. Aboshyan-Sorgho, M. Cantuel, S. Petoud, A. Hauser, C. Piguet, Coord. Chem.
    • Rev. 256 (2012) 1644 1663; (f) L.-J. Xu, G.-T. Xu, Z.-N. Chen, Coord. Chem. Rev. 273 (2014) 47 62.
    • Chem. 281 (2007) 143 203.
    • Photobiol. Sci. 9 (2010) 886 889; (b) D. Sykes, I. S. Tidmarsh, A. Barbieri, I. V. Sazanovich, J. A. Weinstein, M. D.
    • Ward, Inorg. Chem. 50 (2011) 11323 11339; (c) D. Sykes, M. D. Ward, Chem. Commun. 47 (2011) 2279 2281; (d) D. Sykes, S. C. Parker, I. V. Sazanovich, A. Stephenson, J. A. Weinstein, M. D.
    • Ward, Inorg. Chem. 52 (2013) 10500 10511; (e) D. Sykes, A. J. Cankut, N. Mohd Ali, A. Stephenson, S. J. P. Spall, S. C. Parker, J. A. Weinstein, M. D. Ward, Dalton Trans. 43 (2014) 6414 6428.
    • Chem. 47 (2008) 2507 2513; [13] [14] (b) W. Jiang, B. Lou, J. Wang, H. Lv, Z. Bian, C. Huang, Dalton Trans. 40 (2011) 11410 11418; (c) J. E. Jones, R. L. Jenkins, R. S. Hicks, A. J. Hallett, S. J. A. Pope, Dalton Trans.
    • 41 (2012) 10372 10381; (d) G. Yu, Y. Xing, F. Chen, R. Han, J. Wang, Z. Bian, L. Fu, Z. Liu, X. Ai, J.
    • Zhang, C. Huang, ChemPlusChem 78 (2013) 852 859; (e) F.-F. Chen, H.-B. Wei, Z.-Q. Bian, Z.-W. Liu, E. Ma, Z.-N. Chen, C.-H. Huang, Organometallics 33 (2014) 3275 3282; (f) L. Li, S. Zhang, L. Xu, Z.-N. Chen, J. Luo, J. Mater. Chem. C 2 (2014) 1698 1703; (g) Q. Zhao, Y. Liu, Y. Cao, W. Lv, Q. Yu, S. Liu, X. Liu, M. Shi, W. Huang, Adv.
    • Opt. Mater. 3 (2015) 233 240.
    • Gaussian 09, Revision A.1, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E.
    • J. Fox, Gaussian, Inc., Wallingford CT, 2009.
    • (a) S. Sato and M. Wada, Bull. Chem. Soc. Jpn. 43 (1970) 1955; (b) D. Parker, Coord. Chem. Rev. 205 (2000) 109.
    • (a) S. I. Klink, L. Grave, D. N. Reinhoudt, F. C. J. M. van Veggel, M. H. V. Werts, F. A. J. Geurts, J. W. Hofstraat, J. Phys. Chem. A 104 (2000) 5457 5468; (b) G. A. Hebbink, D. N. Reinhoudt, F. C. J. M. van Veggel, Eur. J. Org. Chem.
    • (2001) 4101 4106; (c) S. I. Klink, G. A. Hebbink, L. Grave, F. C. J. M. van Veggel, D. N. Reinhoudt, L.
    • H. Slooff, A. Polman, J. W. Hofstraat, J. Appl. Phys. 86 (1999) 1181 1185.
    • [18] (a) G. M. Davies, S. J. A. Pope, H. Adams, S. Faulkner, M. D. Ward, Inorg. Chem.
    • (c) S. I. Klink, H. Keizer, F. C. J. M. van Veggel, Angew. Chem., Int. Ed. 39 (2000) 4319 4321.
    • A. Beeby, S. Faulkner, Chem. Phys. Lett. 266 (1997) 116 122.
    • (a) A. D. Becke, J. Chem. Phys. 98 (1993) 5648 5652; (b) Ò. Rubio-Pons, Y. Luo, H. Ågren, J. Chem. Phys. 124 (2006) 094310, 1 5.
    • (a) P. J. Hay, W. R. Wadt, J. Chem. Phys. 82 (1985) 270 283; (b) W. R. Wadt, P. J. Hay, J. Chem. Phys. 82 (1985) 284 298; (c) P. J. Hay, W. R. Wadt, J. Chem. Phys. 82 (1985) 299 310.
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