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Braunschweig, Holger; Krummenacher, Ivo; Mailänder, Lisa; Pentecost, Leanne; Vargas, Alfredo (2016)
Publisher: Royal Society of Chemistry
Languages: English
Types: Article
Subjects: QD
Herein, we describe the selective formation of a stable neutral spiroborate radical by one-electron oxidation of the corresponding tetraorganoborate salt Li[B(C4Ph4)2], formally containing a tetrahedral borate center and a s-cis-butadiene radical cation as the spin-bearing site. Spectroscopic and computational methods have been used to determine the spin distribution and the chromism observed in the solid state.
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    • 17 A Cambridge Structural Database (CSD) search with the ConQuest program resulted in no match (accessed February 2, 2016).
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    • 19 L. E. Longobardi, L. Liu, S. Grimme and D. W. Stephan, J. Am. Chem. Soc., 2016, 138, 2500-2503.
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