Remember Me
Or use your Academic/Social account:


Or use your Academic/Social account:


You have just completed your registration at OpenAire.

Before you can login to the site, you will need to activate your account. An e-mail will be sent to you with the proper instructions.


Please note that this site is currently undergoing Beta testing.
Any new content you create is not guaranteed to be present to the final version of the site upon release.

Thank you for your patience,
OpenAire Dev Team.

Close This Message


Verify Password:
Verify E-mail:
*All Fields Are Required.
Please Verify You Are Human:
fbtwitterlinkedinvimeoflicker grey 14rssslideshare1
Andrew, Rhiann; Ferdani, Dominic W.; Ohlin, C. André; Chaplin, Adrian B. (2015)
Publisher: American Chemical Society
Languages: English
Types: Article
Reversible interaction with carbon monoxide results in the onset of dynamic atropisomerism at 298 K in an otherwise static NHC-based rhodium pincer complex, [Rh(C^N^C-(CH2)12)(CO)][BArF4] (1, ArF = 3,5-C6H3(CF3)2). The mechanism of this process has been comprehensively interrogated by a combination of variable-temperature NMR spectroscopy, IR spectroscopy, and computational modeling. In addition, a structural analogue of a high-energy symmetrical intermediate species—invoked in the process but not directly observed spectroscopically—has been prepared and characterized in solution and the solid-state.
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

    • 1 2 3 4 5 6 (a) Dröge, T.; Glorius, F. Angew. Chem. Int. Ed. 2010, 49, 6940-6952; (b) Hahn, F. E.; Jahnke, M. C.
    • Angew. Chem. Int. Ed. 2008, 47, 3122-3172.
    • (a) van Koten, G., Milstein, D. Eds.; Top. Organomet. Chem. 2013, 40, 1-352; (b) Albrecht, M.; Lindner, M. M. Dalton Trans. 2011, 40, 8733-8744; (c) van der Boom, M. E.; Milstein, D. Chem. Rev. 2003, 103, 1759-1792; (d) Albrecht, M.; van Koten, G. Angew. Chem. Int. Ed. 2001, 40, 3750-3781.
    • (a) Poyatos, M.; Mata, J. A.; Peris, E. Chem. Rev. 2009, 109, 3677-3707; (b) Pugh, D.; Danopoulos, A.
    • A. Coord. Chem. Rev. 2007, 251, 610-641; (c) Peris, E.; Crabtree, R. H. Coordin. Chem. Rev. 2004, 248, 2239-2246.
    • Representative examples in catalysis: (a) Filonenko, G. A.; Cosimi, E.; Lefort, L.; Conley, M. P.; Copéret, C.; Lutz, M.; Hensen, E. J. M.; Pidko, E. A. ACS Catal. 2014, 4, 2667-2671; (b) Chianese, A. R.; Drance, M. J.; Jensen, K. H.; McCollom, S. P.; Yusufova, N.; Shaner, S. E.; Shopov, D. Y.; Tendler, J. A.
    • Organometallics 2014, 33, 457-464; (c) Knapp, S. M. M.; Shaner, S. E.; Kim, D.; Shopov, D. Y.; Tendler, J. A.; Pudalov, D. M.; Chianese, A. R. Organometallics 2014, 33, 473-484; (d) Hernández-Juárez, M.; Vaquero, M.; Álvarez, E.; Salazar, V.; Suárez, A. Dalton Trans. 2013, 42, 351-354; (e) Chianese, A. R.; Shaner, S. E.; Tendler, J. A.; Pudalov, D. M.; Shopov, D. Y.; Kim, D.; Rogers, S. L.; Mo, A.
    • Organometallics 2012, 31, 7359-7367; (f) Serra, D.; Cao, P.; Cabrera, J.; Padilla, R.; Rominger, F.; Limbach, M. Organometallics 2011, 30, 1885-1895; (g) Sun, Y.; Koehler, C.; Tan, R.; Annibale, V. T.; Song, D. Chem. Commun. 2011, 47, 8349-8351; (h) Inamoto, K.; Kuroda, J.-I.; Kwon, E.; Hiroya, K.; Doi, T. J. Organomet. Chem. 2009, 694, 389-396; (i) Wei, W.; Qin, Y.; Luo, M.; Xia, P.; Wong, M. S.
    • Organometallics 2008, 27, 2268-2272; (j) Bauer, E. B.; Andavan, G. T. S.; Hollis, T. K.; Rubio, R. J.; Cho, J.; Kuchenbeiser, G. R.; Helgert, T. R.; Letko, C. S.; Tham, F. S. Org Lett 2008, 10, 1175-1178; (k) Loch, J. A.; Albrecht, M.; Peris, E.; Mata, J.; Faller, J. W.; Crabtree, R. H. Organometallics 2002, 21, 700-706.
    • Miecznikowski, J. R.; Gründemann, S.; Albrecht, M.; Mégret, C.; Clot, E.; Faller, J. W.; Eisenstein, O.; Crabtree, R. H. Dalton Trans. 2003, 831-838.
    • (a) Saito, S.; Azumaya, I.; Watarai, N.; Kawasaki, H.; Yamasaki, R. Heterocycles 2009, 79, 531-548; (b) Hahn, F. E.; Jahnke, M. C.; Pape, T. Organometallics 2007, 26, 150-154; (c) Hahn, F. E.; Jahnke, M. C.; Gomez-Benitez, V.; Morales-Morales, D.; Pape, T. Organometallics 2005, 24, 6458-6463; (d) Gründemann, S.; Albrecht, M.; Loch, J. A.; Faller, J. W.; Crabtree, R. H. Organometallics 2001, 20, 5485-5488.
    • Schultz, K. M.; Goldberg, K. I.; Gusev, D. G.; Heinekey, D. M. Organometallics 2011, 30, 1429-1437.
    • Organometallics 2011, 30, 6034-6043.
    • Andrew, R. E.; Chaplin, A. B. Dalton Trans. 2014, 43, 1413-1423.
  • Inferred research data

    The results below are discovered through our pilot algorithms. Let us know how we are doing!

    Title Trust
  • Discovered through pilot similarity algorithms. Send us your feedback.

Share - Bookmark

Funded by projects

Cite this article