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Andrew, Rhiann; Ferdani, Dominic W.; Ohlin, C. André; Chaplin, Adrian B. (2015)
Publisher: American Chemical Society
Languages: English
Types: Article
Subjects:
Identifiers:doi:10.1021/om501292k
Reversible interaction with carbon monoxide results in the onset of dynamic atropisomerism at 298 K in an otherwise static NHC-based rhodium pincer complex, [Rh(C^N^C-(CH2)12)(CO)][BArF4] (1, ArF = 3,5-C6H3(CF3)2). The mechanism of this process has been comprehensively interrogated by a combination of variable-temperature NMR spectroscopy, IR spectroscopy, and computational modeling. In addition, a structural analogue of a high-energy symmetrical intermediate species—invoked in the process but not directly observed spectroscopically—has been prepared and characterized in solution and the solid-state.
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

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