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Sharpe, Helen R.; Geer, Ana M.; Williams, Huw E.L.; Blundell, Toby J.; Lewis, William; Blake, Alexander J.; Kays, Deborah L. (2016)
Publisher: Royal Society of Chemistry
Languages: English
Types: Article
Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.
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    • 21 The mercury drop test was carried out for the manganese catalyst (3). Mercury poisoning is not conclusive for iron because it does not form a stable amalgam: A. A. Mikhailine, M. I. Maishan, A. J. Lough and R. H. Morris, J. Am. Chem. Soc. 2012, 134, 12266.
    • 22 Catalysis carried out with a large excess of cumene does not lead to considerable changes in the conversion. See ESI for experimental details.
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