LOGIN TO YOUR ACCOUNT

Username
Password
Remember Me
Or use your Academic/Social account:

CREATE AN ACCOUNT

Or use your Academic/Social account:

Congratulations!

You have just completed your registration at OpenAire.

Before you can login to the site, you will need to activate your account. An e-mail will be sent to you with the proper instructions.

Important!

Please note that this site is currently undergoing Beta testing.
Any new content you create is not guaranteed to be present to the final version of the site upon release.

Thank you for your patience,
OpenAire Dev Team.

Close This Message

CREATE AN ACCOUNT

Name:
Username:
Password:
Verify Password:
E-mail:
Verify E-mail:
*All Fields Are Required.
Please Verify You Are Human:
fbtwitterlinkedinvimeoflicker grey 14rssslideshare1
Kilpatrick, Alexander; Johnston, David; Green, Jennifer; Tsoureas, Nikolaos; Coles, Martyn; Cloke, Geoff (2016)
Publisher: Elsevier
Languages: English
Types: Article
Subjects: QD0146
A range of iron(II) complexes incorporating the silylated pentalene ligands (Pn†H = 1,4-{SiiPr3}2C8H5 and Pn† = 1,4-{SiiPr3}2C8H4) have been investigated as model molecules/building blocks for metallocene-based polymers. Six complexes have been synthesised and extensively characterised by a range of techniques, including by cyclic voltammetry and X-ray diffraction studies. Amongst these compounds are the homobimetallic [Cp∗Fe]2(μ-Pn†) which is a fused analogue of biferrocene, and the 3d/4s heterobimetallic [Cp∗Fe(η5-Pn†)][K] which forms an organometallic polymer in the solid state. DFT calculations on model mono-Fe(η5-Pn) compounds reveal the charge densities on the uncoordinated carbon atoms of the pentalene ligand, and hence the potential for incorporating these units into heteronuclear bimetallic complexes is assessed.
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

    • T.J. Katz, M. Rosenberger, J. Am. Chem. Soc. 85 (1963) 2030-2031.
    • D.J. Peterson, J. Org. Chem 33 (1968) 780-784.
    • M.B. Gillies, J.E. Tønder, D. Tanner, P.-O. Norrby, J. Org. Chem 67 (2002) 7378-7388.
    • E. Molins, W. Maniukiewicz, C. Miravitlles, M. Mas, J.M. Manríquez, I. Chavez, B. Oelckers, J. Farran, J.L. Brianso, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 52 (1996) 2414- 2416.
    • P. Seiler, J.D. Dunitz, Acta Crystallogr. Sect. B 35 (1979) 1068-1074.
    • C. Miravitlles, E. Molins, W. Maniukiewicz, M. Mas, J.M. Manríquez, I. Chavez, B. Oelckers, A. Alvarez-Larena, J.L. Brianso, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 52 (1996) 3047-3049.
    • Oelckers, E. Molins, C. Miravitlles, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 52 (1996) 2754-2757.
    • M.R. Churchill, K.K.G. Lin, Inorg. Chem. 12 (1973) 2274-2279.
    • J.D. Smith, in:, Advances in Organometallic Chemistry, Elsevier, 1998, pp. 267-348.
    • S. Jones, P. Roussel, T. Hascall, D. O'Hare, Organometallics 25 (2006) 221-229.
    • O.T. Summerscales, D.R. Johnston, F.G.N. Cloke, P.B. Hitchcock, Organometallics 27 (2008) 5612-5618.
    • J.C. Green, M.L.H. Green, G. Parkin, Chem. Commun. 48 (2012) 11481-11503.
    • T.J. Katz, M. Rosenberger, R.K. O'Hara, J. Am. Chem. Soc. 86 (1964) 249-252.
    • F.G.N. Cloke, Pure Appl. Chem. 73 (2001) 233-238.
    • J.M. O'Connor, C.P. Casey, Chem. Rev. 87 (1987) 307-318.
    • Acta 363 (2010) 2222-2232.
    • W.E. Geiger, F. Barrière, Acc. Chem. Res. 43 (2010) 1030-1039.
    • R.G. Compton, C.E. Banks, Understanding Voltammetry, 2nd ed., Imperial College Press, 2011.
    • Organomet. Chem. 142 (1977) 81-87.
    • Phys. Chem. B 103 (2011) 6713-6722.
    • S. Bendjaballah, S. Kahlal, K. Costuas, E. Bévillon, J.-Y. Saillard, Chem.-Eur. J. 12 (2006) 2048-2065.
    • K.B. Wiberg, P.R. Rablen, J. Comput. Chem. 14 (1993) 1504-1518.
    • R.S. Mulliken, J. Chem. Phys. 36 (1962) 3428-3439.
    • F.L. Hirshfeld, Theoret. Chim. Acta 44 (1977) 129-138.
    • C. Fonseca Guerra, J.W. Handgraaf, E.J. Baerends, F.M. Bickelhaupt, J. Comput. Chem. 25 (1993) 189-210.
    • F.G.N. Cloke, M.C. Kuchta, R.M. Harker, P.B. Hitchcock, J.S. Parry, Organometallics 19 (2000) 5795-5798.
    • K. Jonas, P. Klusmann, R. Goddard, Z. Naturforsch. B 50 (1995) 394-404.
    • M. Schlosser, J.R. Hartmann, Angew. Chem. Int. Ed. Engl. 12 (1973) 508-509.
    • R.B. King, M.B. Bisnette, J. Organomet. Chem. 8 (1967) 287-297.
    • P. Kovacic, N.O. Brace, J. Am. Chem. Soc. 76 (1954) 5491-5494.
    • S.J. Coles, P.A. Gale, Chem. Sci. 3 (2012) 683-689.
    • Rigaku, CrystalClear (2011).
    • Bruker-AXS BV, Collect (1997).
    • Z. Otwinowski, W. Minor, Methods Enzymol. 276 (1997) 307.
    • R.H. Blessing, Acta Crystallogr., A, Found. Crystallogr. 51 (1995) 33-38.
    • L.J. Farrugia, J. Appl. Crystallogr. 32 (1999) 837-838.
    • SCM, Amsterdam Density Functional, ADF (2006).
    • S.H. Vosko, L. Wilk, M. Nusair, Can. J. Phys. 58 (1980) 1200-1211.
    • A. Becke, Phys. Rev., A 38 (1988) 3098-3100.
    • J.P. Perdew, Phys. Rev. B 33 (1986) 8822-8824.
  • No related research data.
  • No similar publications.

Share - Bookmark

Funded by projects

  • EC | RTCO
  • RCUK | Activation and Functionali...

Cite this article