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Parker, James; Jones, Richard G.; Holder, Simon J. (2000)
Languages: English
Types: Article
Subjects: QD
Identifiers:doi:10.1021/ma000507u
  • The results below are discovered through our pilot algorithms. Let us know how we are doing!

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    • (17) PMPS: Mn ) 11 700, Mw ) 165 700, and Mw/Mn ) 14. BrMePMPS: Mn ) 5200, Mw ) 8500, and Mw/Mn ) 1.6. BrMe substitution ) 33% of phenyl groups by 1H NMR. Low DP graft copolymer: Mn ) 9700, Mw ) 37 200, and Mw/Mn ) 3.8. High DP graft copolymer (includes both peaks): Mn ) 60 800, Mw ) 150 300, and Mw/Mn ) 2.4. SEC's were acquired against linear polystyrene standards with a UV detector and as such do not take into account hydrodynamic differences between the linear and graft copolymers. A typical polymerization procedure is given as Supporting Information.
    • (18) It should also be noted that the monomodal distribution for the low DP copolymers and the multimodal distribution for inefficient initiation. A fuller discussion of initiator efficiency and the relative activity of the grafting sites and chains will be published in a full paper at a later date.
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